Gonadal histology and serum vitellogenin levels of bigeye tuna Thunnus obesus from the Northern Pacific Ocean--absence of endocrine disruption bio-indicators     

Hashimoto S  Kurihara R  Strüssmann CA  Yamasaki T  Soyano K  Hara A  Shiraishi H  Morita M 《Marine pollution bulletin》2003,46(4):459-465

Endocrine disrupting chemicals such as organochlorines have been detected in a large number of marine fish. Histological observation of the gonads, measurement of serum vitellogenin (VTG) level and of liver polychlorinated biphenyl (PCB) content were performed to evaluate the reproductive health and the contamination with endocrine disruptors in bigeye tuna Thunnus obesus, collected in the northern Pacific Ocean in 1999 and 2000. Abnormalities commonly found in species affected by endocrine disruptors such as the presence of oocytes in the testis or elevated serum VTG levels were not found in any of males examined. Both males and females had only small amounts of liver PCB content. The results suggest that currently there is little if any risk of organochlorine contamination or endocrine disruption of gonadal function in bigeye tuna from the northern Pacific Ocean. However, further studies are necessary to evaluate the health status of the open sea fishery resources.  相似文献   

Benthic primary producers--a neglected environmental problem in Mediterranean maricultures?     

Holmer M  Pérez M  Duarte CM 《Marine pollution bulletin》2003,46(11):1372-1376

Marine fish farming is increasing rapidly in the Mediterranean and in contrast to the Atlantic the coastal zone in the Mediterranean is characterized by clear waters with high transparency. This allows benthic primary producers such as the slow-growing seagrass Posidonia oceanica to grow at large depths at locations suitable for fish farming and generating a conflict between the conservation of these meadows and the growth of aquaculture operations in the Mediterranean. In this paper we review the current knowledge on environmental interactions between fish farming and benthic primary producers with particular focus on P. oceanica, as this seagrass is a key component along Mediterranean coasts. The recovery times of P. oceanica are very long, in the order of centuries, and losses of this species are thus considered to be irreversible at managerial time scales.  相似文献   

Adakite-like signature of Late Miocene intrusions at the Los Pelambres giant porphyry copper deposit in the Andes of central Chile: metallogenic implications   总被引：7，自引：0，他引：7  

Martin?Reich  Miguel?A.?ParadaEmail author  Carlos?Palacios  Andreas?Dietrich  Frank?Schultz  Bernd?Lehmann 《Mineralium Deposita》2003,38(7):876-885

Adakite-like features are recognized in the Late Miocene (~10 Ma) porphyritic intrusions of the Los Pelambres giant porphyry copper deposit, central Chile (32°S). Located within the southern portion of the flat-slab segment (28–33°S) of the Chilean Andes, the Al- and Na-rich porphyries of Los Pelambres display distinctly higher Sr/Y (~100–300) and La_N/Yb_N (~25–60) ratios than contemporaneous and barren magmatic units (e.g., La Gloria pluton, Cerro Aconcagua volcanic rocks) of the same Andean magmatic belt. Strong fractionation of heavy rare earth elements (HREE), absence of Eu anomalies, high Sr/Y and Zr/Sm and low Nb/Ta ratios suggest melt extraction from a garnet-amphibolite source. The Late-Miocene adakite-like porphyritic intrusions at Los Pelambres formed closely related in time and space to the subduction of the Juan Fernández Ridge (JFR) hotspot chain along the Chilean margin. Current tectonic reconstructions reveal that, at the time of formation of the Los Pelambres rocks, a W-E segment of the JFR started to subduct beneath them, producing a slow-down of a previously rapid southward migration of a NE-ridge—trench collision. These particular tectonic conditions are favorable for the origin of the Los Pelambres porphyry suite by melting of subducting young hotspot rocks under flat-slab conditions. The incorporation of crustal components into the oceanic lithopheric magma source by subduction erosion is evidenced by the Sr-Nd isotope composition of the Los Pelambres rocks different from the MORB signatures of true adakites. A close relationship apparently exists between the origin of this adakite-like magmatism and the source of the mineralization in the Los Pelambres porphyry copper deposit.Editorial handling: R.J. Goldfarb  相似文献   

Chemical Mechanism Development: Laboratory Studies and Model Applications     

Harald Geiger  Ian Barnes  Karl H. Becker  Birger Bohn  Theo Brauers  Birgit Donner  Hans-Peter Dorn  Manfred Elend  Carlos M. Freitas Dinis  Dirk Grossmann  Heinz Hass  Holger Hein  Axel Hoffmann  Lars Hoppe  Frank Hülsemann  Dieter Kley  Björn Klotz  Hans G. Libuda  Tobias Maurer  Djuro Mihelcic  Geert K. Moortgat  Romeo Olariu  Peter Neeb  Dirk Poppe  Lars Ruppert  Claudia G. Sauer  Oleg Shestakov  Holger Somnitz  William R. Stockwell  Lars P. Thüner  Andreas Wahner  Peter Wiesen  Friedhelm Zabel  Reinhard Zellner  Cornelius Zetzsch 《Journal of Atmospheric Chemistry》2002,42(1):323-357

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.  相似文献   

Enforcing smoothness and assessing uncertainty in non-linear one-dimensional prestack seismic inversion   总被引：1，自引：0，他引：1  

Omar J. Varela  Carlos Torres-Verdín  Mrinal K. Sen 《Geophysical Prospecting》2006,54(3):239-259

Estimation of elastic properties of rock formations from surface seismic amplitude measurements remains a subject of interest for the exploration and development of hydrocarbon reservoirs. This paper develops a global inversion technique to estimate and appraise 1D distributions of compressional‐wave velocity, shear‐wave velocity and bulk density, from normal‐moveout‐corrected PP prestack surface seismic amplitude measurements. Specific objectives are: (a) to evaluate the efficiency of the minimization algorithm (b) to appraise the impact of various data misfit functions, and (c) to assess the effect of the degree and type of smoothness criterion enforced by the inversion. Numerical experiments show that very fast simulated annealing is the most efficient minimization technique among alternative approaches considered for global inversion. It is also found that an adequate choice of data misfit function is necessary for a reliable and efficient match of noisy and sparse seismic amplitude measurements. Several procedures are considered to enforce smoothness of the estimated 1D distributions of elastic parameters, including predefined quadratic measures of length, flatness and roughness. Based on the general analysis of global inversion techniques, we introduce a new stochastic inversion algorithm that initializes the search for the minimum with constrained random distributions of elastic parameters and enforces predefined autocorrelation functions (semivariograms). This strategy readily lends itself to the assessment of model uncertainty. The new global inversion algorithm is successfully tested on noisy synthetic amplitude data. Moreover, we present a feasibility analysis of the resolution and uncertainty of prestack seismic amplitude data to infer 1D distributions of elastic parameters measured with wireline logs in the deepwater Gulf of Mexico. The new global inversion algorithm is computationally more efficient than the alternative global inversion procedures considered here.  相似文献   

Seismic quantification of the explosions that destroyed the dome of Volcán de Colima, Mexico, in July–August 2003     

Vyacheslav M. Zobin  Carlos J. Navarro-Ochoa  Gabriel A. Reyes-Dávila 《Bulletin of Volcanology》2006,69(2):141-147

In July–August 2003, the andesitic lava dome at Volcán de Colima, México, was destroyed by a sequence of explosions that replaced the 2×10⁶ m³ dome with a crater 200 m across and 30 m deep. The two strongest explosions occurred on July 17 and August 28. The initial low-frequency impulses that they produced, which were recorded on broadband seismic records, allowed an estimation of the counter forces of the initiating process as being equal to 0.3×10¹¹ N and 1×10¹¹ N for the July and August events, respectively. The seismic characteristics follow the Nishimura-Hamaguchi scaling law for volcanic explosions, reflecting self-similarity in the processes initiating explosive events. The results also show that counter forces can discriminate between the sizes of explosive eruptions that are assigned the same magnitude by conventional methods of classification such as the Volcanic Explosivity Index. The increasing use of broadband seismometers may therefore provide the basis for using counter forces to determine the magnitude of explosive eruptions.  相似文献   

Pahoehoe flows from the central Paraná Continental Flood Basalts     

Breno L. Waichel  Evandro F. de Lima  Romulo Lubachesky  Carlos A. Sommer 《Bulletin of Volcanology》2006,68(7-8):599-610

Inflated and compound pahoehoe flows have been identified within the central Paraná Continental Flood Basalts based upon their morphology, surface features, and internal zonation. Pahoehoe flow features have been studied at five localities in the western portion of Paraná State, Brazil: Ponte Queimada, Toledo, Rio Quitéria, Matelandia and Cascavel. We have interpreted the newly recognized flow features using concepts of Hawaiian pahoehoe formation and emplacement that have been previously applied to the Columbia River Basalt and Deccan Plateau. Surface features and/or internal structure typical from pahoehoe lavas are observed in all studied areas and features like inflation clefts, squeeze-ups, breakouts, and P-type lobes with two levels of pipe vesicles are indicative of inflation in these flows. The thinner, compound pahoehoe flows are predominantly composed of P-type lobes and probably emerged at the end of large inflated flows on shallow slopes. The presence of vesicular cores in the majority of compound lobes and the common occurrence of segregation structures suggests high water content in the pahoehoe lavas from the central PCFB. More volcanological studies are necessary to determinate the rheology of lavas and refine emplacement models.Editorial responsibility: C. Kilburn  相似文献   

Comments on: ‘The Neutral, Barotropic Planetary Boundary Layer, Capped by a Low-Level Inversion’ by G. D. Hess, Boundary-Layer Meteorology (2004) 110, pp. 319–355     

Juan Carlos Bergmann 《Boundary-Layer Meteorology》2006,119(1):171-179

Precision measurements indicate that the stability capping of the neutral planetary boundary layer (PBL) that leads to a reduced PBL height is caused by the very stable upper part of the PBL, rather than by an overlying inversion. Radiative processes related to liquid water in boundary-layer clouds seem to play the key role for the formation of the stable upper PBL. The famous Leipzig Profile – generally considered as an example of a neutral PBL – has been included in Hess’s analysis because its PBL height is considerably lower than the ca. 3000 m to be expected by numerical models in truly neutral conditions. An analysis of the original observations reveals that the Leipzig PBL was stable and that it can be consistently treated as a ‘normal’ stable PBL with a height of ca. 700 m. A further finding is that the super-geostrophic PBL wind speed maxima predicted by almost all models are not observed in near-steady-state conditions. For the ‘ranking’ of analytical models versus numerical models, the comparisons with measurements show that the analytical models perform comparably well and even partially better than the numerical models.  相似文献   

Coupled thermal, hydraulic and geochemical evolution of pyritic tailings in unsaturated column experiments     

Patricia Acero  Carlos Ayora  Jesús Carrera 《Geochimica et cosmochimica acta》2007,71(22):5325-5338

The evolution of pore-water and the composition of solid phases in the vadose zone of pyritic tailings was studied by means of unsaturated column experiments. Several columns of water-saturated mine tailings were dried during 125 days under controlled laboratory conditions. The columns were dismantled at four successive drying stages and the evolution of pore-water, mineralogy, water content and temperature was characterized.Sulfide and aluminosilicate minerals present in the waste dissolved, releasing sulfate and other solutes (mainly Fe, Zn, Cu, Al, Mg and Ca) to the pore-water. Evaporation caused a crust of efflorescent, water-soluble sulfates to develop over the complete top surface of the columns and into the pores of the underlying waste material. This crust, which has also been identified in the field, changed the hydraulic properties of the tailings and produced a decrease in the evaporation rate of the columns. Moreover, these water-soluble precipitates (mainly rozenite, szomolnokite, halotrichite, hexahydrite, mirabilite and gypsum) acted as temporary sinks for Cd, Pb, Co and Ni, which could be released to the surface run-off or the groundwaters during rainfall events under field conditions.Pore-water evolution was determined not only by geochemical processes (dissolution of sulfides and aluminosilicates, precipitation of secondary phases) but also by thermal and hydraulic processes. Progressive dilution was observed in the lower part of the columns. Dilution was caused by the thermally driven vapor flux from the top of the column to its colder bottom and subsequent condensation therein. This process, which may also occur in tailings under sub-arid climate, played a key role on the evolution of pore-water with increasing drying.  相似文献   

Deconstructing the best case scenario: lessons from water politics in La Paz-El Alto, Bolivia     

Nina Laurie  Carlos Crespo 《Geoforum》2007,38(5):841-854

For nearly a decade the La Paz-El Alto concession in Bolivia was heralded by donor organizations, the state and the commercial water industry alike as an emblematic ‘pro-poor’ water concession under the private sector model. Managed by one of the largest water multinationals in the world (the French company Suez), the network was extended beyond the new connections required by the original ‘pro-poor’ contract, acclaimed as a pioneer of new pro-poor technologies and frequently disseminated internationally as an example of best practice. This paper analyses the La Paz-El Alto concession’s pro-poor image focusing on issues of social exclusion and network extension, contract negotiation, participation and transparency. It documents the rise of social protest about the concession and critiques the failure of neoliberal regulatory systems to promote accountability to the poor. In the context of the continued transnationalisation of the water industry the paper highlights the need for new mechanisms and delivery models to ensure greater national control over private companies and the development of a framework for international water governance.  相似文献